Oximate metal complexes breaking the limiting esterolytic reactivity of oximate anions.
نویسندگان
چکیده
Zinc(II) and cadmium(II) complexes of a tridentate oximate ligand cleave 4-nitrophenyl acetate with rate constants surpassing by two orders of magnitude those reported as the maximum possible level for highly basic free oximate anions as a result of removal of the "solvational imbalance" of the nucleophile by metal coordination.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 49 70 شماره
صفحات -
تاریخ انتشار 2013